1. 方法概述：
本检验方法适用于谷类、干豆类、干辣椒等食品中373项农药多重残留分析 。
2. 检验方法：
样品采用一步法快速萃取柱(FaPEx-cer)净化后，以液相色谱串级质谱仪(LC/MS/MS)及气相色谱串级质谱仪(GC/MS/MS)外标法分析。
3.设备：
3.1 液相色谱串级质谱仪：
3.2 离子源：电喷雾电离源(ESI) 。
3.3色谱柱：CORTECS UPLC® ，C18，1.6 µm，内径2.1 mm × 10 cm，或 同级品 。
3.4保护柱：CORTECS UPLC® ,C18，1.6 µm，内径2.1 mm × 5 mm ， 或同级品 。
3.5气相色谱串联质谱仪：
3.6离子源：电子轰击源(EI) 。
3.7色谱柱：DB-5MS UI毛细管，内膜厚度0.25 μm，内径0.25 mm×30 m ，或同级品。
3. 前处理操作步骤：
3.1.粉碎
谷类、干豆类、干辣椒类样品以粉碎机磨粉，均质后检体取适量进行下述萃取及净化步骤，若无法于当天进行分析，应保存于 -20℃中 。
3.2. 干豆类、谷类及干辣椒类：
取均质后称重约0.5 g，置于离心管中，先加入去离子水1mL，混匀并静置10分钟再加入含1%醋酸之乙腈溶液5 mL，盖上离心管盖，随即旋涡混匀30秒后，将萃取液注入一步法净化柱FaPEx-cer，流速控制为1滴/秒，收集全部流出液，作为检液原液。
取检液原液1 mL ， 以滤膜过滤，上机以LC/MS/MS分析。
另取检液原液1 mL，以氮气吹至刚干，残留物以丙酮：正己烷(1:1, v/v) 1mL溶解，混合均匀，经滤膜过滤，上机以GC/MS/MS分析。
4.仪器分析条件
4.1 液相层析串联质谱分析测定条件：
移动相溶液：A液与B液以下列条件进行梯度分析
时间(min) | A (%) | B (%) |
0.0 → 2.0 | 99 → 50 | 1 → 50 |
2.0 → 8.0 | 50 → 30 | 50 → 70 |
8.0 → 10.0 | 30 → 1 | 70 → 99 |
10.0 → 13.0 | 1 → 1 | 99 → 99 |
13.0 → 13.5 | 1 → 99 | 99 → 1 |
13.5 → 15.0 | 99 → 99 | 1 → 1 |
移动相流速：0.3 mL/min 。
注入量：5 μL 。
毛细管电压(Capillary voltage) ：
电洒离子化正离子(ESI＋)采用3.5 kV ，
电洒离子化负离子(ESI－)采用1.6 kV 。
离子源温度(Ion source temperature)：150°C 。
溶媒挥散温度(Desolvation temperature)：450°C 。
进样锥气体流速(Cone gas flow)：30 L/hr 。
溶媒挥散流速(Desolvation flow)：900 L/hr 。
侦测模式：多重反应侦测(multiple reaction monitoring, MRM)。
4.2 GC/MS/MS ：气相层析串联质谱分析测定条件：
层析管：DB-5MSUI毛细管，内膜厚度0.25 μm，内径0.25 mm × 30 m。
层析管温度：初温：60°C， 1 min；
升温速率：40°C/min；
中温：170°C；
升温速率：10°C/min；
终温：310°C，2.25 min 。
移动相流速：氦气，1 mL/min 。
注入器温度(Injector temperature)：280°C 。
注入模式：不分流(splitless) 。
注入量：1 μL 。
离子化模式：电子撞击游离(EI)，70 eV 。
离子源温度：300°C 。
侦测模式：多重反应侦测，侦测离子对及碰撞能量如表三。
注1：芬普尼之基质匹配检量线制作时，选择适当之标准溶液添加 。
注2：上述测定条件分析不适时，可依所使用之仪器，设定适合的条件。
5、药剂清单（回收率等结果，联络索取）
编号 | 英文名称 | 中文名称 | 分析方法 |
1 | Abamectin | 阿维菌素 | LC-MS/MS |
2 | Acephate | 乙酰甲胺lin磷 | LC-MS/MS |
3 | Acetamiprid | 啶虫脒 | LC-MS/MS |
4 | Acibenzolar-S-methyl | 阿拉酸式苯-S-甲基 | LC-MS/MS |
5 | Aldicarb | 涕灭wei威 | LC-MS/MS |
6 | Aldicarbsulfone | 涕灭wei威砜 | LC-MS/MS |
7 | Aldicarbsulfoxide | 涕灭wei威亚砜 | LC-MS/MS |
8 | Alloxydim(sodium) | 禾草灭 | LC-MS/MS |
9 | Ametoctradin | 唑嘧菌胺 | LC-MS/MS |
10 | Ametryn | 莠灭净 | LC-MS/MS |
11 | Amisulbrom | 吲唑磺菌胺 | LC-MS/MS |
12 | Atrazine | 莠去津 | LC-MS/MS |
13 | Azoxystrobin | 嘧菌酯 | LC-MS/MS |
14 | Benalaxyl | 苯霜灵 | LC-MS/MS |
15 | Bendiocarb | 恶虫威 | LC-MS/MS |
16 | Benfuracarb | 丙硫克百wei威 | LC-MS/MS |
17 | Bensulfuron-methyl | 苄嘧磺隆 | LC-MS/MS |
18 | Benthiazole | 苯噻硫氰 | LC-MS/MS |
19 | Bifenazate | 联苯肼酯 | LC-MS/MS |
20 | Boscalid | 啶酰菌胺 | LC-MS/MS |
21 | Bufencarb | 合杀威 | LC-MS/MS |
22 | Buprofezin | 噻嗪酮 | LC-MS/MS |
23 | Butocarboxim | 丁酮威 | LC-MS/MS |
24 | Carbaryl | 甲萘威 | LC-MS/MS |
25 | Carbendazim | 多菌灵 | LC-MS/MS |
26 | Carbofuran | 克百wei威 | LC-MS/MS |
27 | 3-ketoCarbofuran | 3-酮基呋nan喃丹 | LC-MS/MS |
28 | 3-OHCarbofuran | 3-羟基呋nan喃丹 | LC-MS/MS |
29 | Carbosulfan | 丁硫克bai百威 | LC-MS/MS |
30 | Carfentrazone-ethyl | 唑草酮 | LC-MS/MS |
31 | Carpropamid | 加普胺 | LC-MS/MS |
32 | Chlorantraniliprole | 氯虫苯甲酰胺 | LC-MS/MS |
33 | Chlorfluazuron | 氟啶脲 | LC-MS/MS |
34 | Chromafenozide | 环虫酰肼 | LC-MS/MS |
35 | Cinern I | 除虫菊精 I | LC-MS/MS |
36 | Cinern II | 除虫菊精 II | LC-MS/MS |
37 | Cinosulfuron | 醚磺隆 | LC-MS/MS |
38 | Clethodim | 烯草酮 | LC-MS/MS |
39 | Clofentezine | 四螨嗪 | LC-MS/MS |
40 | Clomazone | 异恶草酮 | LC-MS/MS |
41 | Clomeprop | 氯甲酰草胺 | LC-MS/MS |
42 | Clothianidin | 噻虫胺 | LC-MS/MS |
43 | Cyanazine | 氰草津 | LC-MS/MS |
44 | Cyazofamid | 氰霜唑 | LC-MS/MS |
45 | Cyclosulfamuron | 环丙嘧磺隆 | LC-MS/MS |
46 | Cycloxydim | 噻草酮 | LC-MS/MS |
47 | Cyflufenamid | 环氟菌胺 | LC-MS/MS |
48 | Cyflumetofen | 丁氟螨酯 | LC-MS/MS |
49 | Cymoxanil | 霜脲氰 | LC-MS/MS |
50 | Cyprodinil | 嘧菌环胺 | LC-MS/MS |
51 | Demeton-S-methyl | 甲基内xi吸磷 | LC-MS/MS |
52 | Dicrotophos | 百治lin磷 | LC-MS/MS |
53 | Dimethenamid | 二甲吩草胺 | LC-MS/MS |
54 | Dimethoate | 乐果 | LC-MS/MS |
55 | Dimethomorph | 烯酰吗啉 | LC-MS/MS |
56 | Dinotefuran | 呋虫胺 | LC-MS/MS |
57 | Diuron | 敌草隆 | LC-MS/MS |
58 | Dymron | 杀草隆 | LC-MS/MS |
59 | EmamectinbenzoateB1a | 甲氨基阿维菌素B1a苯甲酸盐 | LC-MS/MS |
60 | EmamectinbenzoateB1b | 甲氨基阿维菌素B1b苯甲酸盐 | LC-MS/MS |
61 | Ethiprole | 乙虫腈 | LC-MS/MS |
62 | Ethirimol | 乙嘧酚 | LC-MS/MS |
63 | Etoxazole | 乙螨唑 | LC-MS/MS |
64 | Famoxadone | 噁唑菌酮 | LC-MS/MS |
65 | Fenamiphos | 苯线lin磷 | LC-MS/MS |
66 | Fenazaquin | 喹螨醚 | LC-MS/MS |
67 | Fenbutatin-oxide | 苯丁锡 | LC-MS/MS |
68 | Fenhexamid | 环酰菌胺 | LC-MS/MS |
69 | Fenobucarb | 仲丁威 | LC-MS/MS |
70 | Fenothiocarb | 苯硫威 | LC-MS/MS |
71 | Fenoxanil | 稻瘟酰胺 | LC-MS/MS |
72 | Fenoxycarb | 苯氧威 | LC-MS/MS |
73 | Fenpyroximate | 唑螨酯 | LC-MS/MS |
74 | Fenthion | 倍硫lin磷 | LC-MS/MS |
75 | Ferimzone | 嘧菌腙 | LC-MS/MS |
76 | Flazasulfuron | 啶嘧黄隆 | LC-MS/MS |
77 | Flonicamid | 氟啶虫酰胺 | LC-MS/MS |
78 | Fluazifop-P-butyl | 吡氟禾草灵 | LC-MS/MS |
79 | Fludioxonil | 咯菌腈 | LC-MS/MS |
80 | Flufenoxuron | 氟虫脲 | LC-MS/MS |
81 | Fluopicolide | 氟吡菌胺 | LC-MS/MS |
82 | Fluopyram | 氟吡菌酰胺 | LC-MS/MS |
83 | Flupyradifurone | 氟吡呋喃酮 | LC-MS/MS |
84 | Flusilazole | 氟硅唑 | LC-MS/MS |
85 | Flutriafol | 粉唑醇 | LC-MS/MS |
86 | Formetanate | 伐虫脒 | LC-MS/MS |
87 | Fosthiazate | 噻唑磷 | LC-MS/MS |
88 | Furametpyr | 呋吡菌胺 | LC-MS/MS |
89 | Haloxyfop-methyl | 氟吡甲禾灵 | LC-MS/MS |
90 | Hexaconazole | 己唑醇 | LC-MS/MS |
91 | Hexaflumuron | 氟铃脲 | LC-MS/MS |
92 | Hexythiazox | 噻螨酮 | LC-MS/MS |
93 | Imazalil | 抑霉唑 | LC-MS/MS |
94 | Imidacloprid | 吡虫啉 | LC-MS/MS |
95 | Indoxacarb | 茚虫威 | LC-MS/MS |
96 | Iprovalicarb | 缬霉威 | LC-MS/MS |
97 | Isazofos | 氯唑lin磷 | LC-MS/MS |
98 | Isoprocarb | 异丙威 | LC-MS/MS |
99 | Isopyrazam | 吡唑萘菌胺 | LC-MS/MS |
100 | Isouron | 异恶隆 | LC-MS/MS |
101 | Isoxaflutole | 异恶唑草酮 | LC-MS/MS |
102 | JasmolinI | 茉酮菊素I | LC-MS/MS |
103 | JasmolinII | 茉酮菊素II | LC-MS/MS |
104 | Linuron | 利谷隆 | LC-MS/MS |
105 | Mandipropamid | 双炔酰菌胺 | LC-MS/MS |
106 | Mecarbam | 灭蚜磷 | LC-MS/MS |
107 | Mepanipyrim | 嘧菌胺 | LC-MS/MS |
108 | Metaflumizone | 氰氟虫腙 | LC-MS/MS |
109 | Metalaxyl | 甲霜灵 | LC-MS/MS |
110 | Metconazole-cis | 顺式-叶菌唑 | LC-MS/MS |
111 | Methamidophos | 甲胺lin磷 | LC-MS/MS |
112 | Methiocarb | 甲硫威 | LC-MS/MS |
113 | Methomyl | 灭多威 | LC-MS/MS |
114 | Methoprene | 烯虫酯 | LC-MS/MS |
115 | Methoxyfenozide | 甲氧虫酰肼 | LC-MS/MS |
116 | Metobromuron | 溴谷隆 | LC-MS/MS |
117 | Metolcarb | 速灭wei威 | LC-MS/MS |
118 | Metrafenone | 苯菌酮 | LC-MS/MS |
119 | Metribuzin | 嗪草酮 | LC-MS/MS |
120 | Mevinphos | 速灭磷 | LC-MS/MS |
121 | Monocrotophos | 久效lin磷 | LC-MS/MS |
122 | MPMC(Xylylcarb) | 灭杀威 | LC-MS/MS |
123 | Norflurazon | 哒草伏 | LC-MS/MS |
124 | Novaluron | 氟酰脲 | LC-MS/MS |
125 | Omethoate | 氧乐果 | LC-MS/MS |
126 | Oxamyl | 杀线威 | LC-MS/MS |
127 | Oxycarboxin | 氧化萎锈灵 | LC-MS/MS |
128 | Oxydemeton-Methyl | 亚砜磷 | LC-MS/MS |
129 | Pencycuron | 戊菌隆 | LC-MS/MS |
130 | Penoxsulam | 五氟磺草胺 | LC-MS/MS |
131 | Phosphamidon | 磷an胺 | LC-MS/MS |
132 | Phoxim | 辛硫lin磷 | LC-MS/MS |
133 | Piperonylbutoxide | 增效醚 | LC-MS/MS |
134 | Pirimicarb | 抗蚜wei威 | LC-MS/MS |
135 | Pretilachlor | 丙草胺 | LC-MS/MS |
136 | Probenazole | 烯丙苯噻唑 | LC-MS/MS |
137 | Prochloraz | 咪酰胺 | LC-MS/MS |
138 | Profenophos | 丙溴磷 | LC-MS/MS |
139 | Promecarb | 猛杀威 | LC-MS/MS |
140 | Propamocarb hydrochloride | 霜霉威盐酸盐 | LC-MS/MS |
141 | Propanil | 敌稗 | LC-MS/MS |
142 | Propargite | 炔螨特 | LC-MS/MS |
143 | Propoxur | 残杀威 | LC-MS/MS |
144 | Proquinazid | 丙氧喹啉 | LC-MS/MS |
145 | Pymetrozine | 吡蚜酮 | LC-MS/MS |
146 | Pyraclostrobin | 吡唑醚菌酯 | LC-MS/MS |
147 | Pyrazosulfuron-ethyl | 吡嘧磺隆 | LC-MS/MS |
148 | PyrethrinI | 除虫菊素I | LC-MS/MS |
149 | PyrethrinII | 除虫菊素II | LC-MS/MS |
150 | Pyribencarb | 吡菌苯威 | LC-MS/MS |
151 | Pyridaben | 哒螨灵 | LC-MS/MS |
152 | Pyrifluquinazon | 吡啶喹唑啉 | LC-MS/MS |
153 | Pyridate | 哒草特 | LC-MS/MS |
154 | Pyrifenox | 碇斑肟 | LC-MS/MS |
155 | Quinoxyfen | 喹氧灵 | LC-MS/MS |
156 | Quizalofop-ethyl | 喹禾灵 | LC-MS/MS |
157 | Rotenone | 鱼藤酮 | LC-MS/MS |
158 | Saflufenacil | 苯嘧磺草胺 | LC-MS/MS |
159 | Sethoxydim | 烯禾啶 | LC-MS/MS |
160 | Simazine | 西玛津 | LC-MS/MS |
161 | SpinetoramJ | 乙基多杀菌素 J | LC-MS/MS |
162 | SpinetoramL | 乙基多杀菌素 L | LC-MS/MS |
163 | SpinosadA | 多杀霉素A | LC-MS/MS |
164 | SpinosadD | 多杀霉素D | LC-MS/MS |
165 | Spirodiclofen | 螺螨酯 | LC-MS/MS |
166 | Spiromesifen | 螺甲螨酯 | LC-MS/MS |
167 | Spirotetramat | 螺虫乙酯 | LC-MS/MS |
168 | Sulfoxaflor | 氟啶虫胺腈 | LC-MS/MS |
169 | Tebufenozide | 虫酰肼 | LC-MS/MS |
170 | Tebufenpyrad | 吡螨胺 | LC-MS/MS |
171 | Tepraloxydim | 得杀草 | LC-MS/MS |
172 | Thiabendazole | 噻菌灵 | LC-MS/MS |
173 | Thiacloprid | 噻虫啉 | LC-MS/MS |
174 | Thiamethoxam | 噻虫嗪 | LC-MS/MS |
175 | Thiobencarb | 禾草丹 | LC-MS/MS |
176 | Thiodicarb | 硫双威 | LC-MS/MS |
177 | Thiofanox | 久效wei威砜 | LC-MS/MS |
178 | Tolfenpyrad | 唑虫酰胺 | LC-MS/MS |
179 | Tolyfluanid | 对甲抑菌灵 | LC-MS/MS |
180 | Trichlorfon | 敌百chong虫 | LC-MS/MS |
181 | Tricyclazole | 三环唑 | LC-MS/MS |
182 | Trifloxystrobin | 肟菌酯 | LC-MS/MS |
183 | Triforine | 嗪氨灵 | LC-MS/MS |
184 | Vamidothion | 蚜灭磷 | LC-MS/MS |
185 | XMC(Macbal) | 二甲威 | LC-MS/MS |
186 | Zoxamide | 苯酰菌胺 | LC-MS/MS |
187 | Acequinocyl- | 羟基灭螨醌 | LC-MS/MS |
188 | Bentazone | 灭草松 | LC-MS/MS |
189 | Diflubenzuron | 除虫脲 | LC-MS/MS |
190 | Fipronil | 氟虫腈 | LC-MS/MS |
191 | Fipronil-sulfone | 氟虫腈砜 | LC-MS/MS |
192 | Fluazinam | 氟啶胺 | LC-MS/MS |
193 | Flubendiamide | 氟苯虫酰胺 | LC-MS/MS |
194 | Lufenuron | 虱螨脲 | LC-MS/MS |
195 | Penthiopyrad | 吡噻菌胺 | LC-MS/MS |
196 | Teflubenzuron | 氟苯脲 | LC-MS/MS |
197 | Acetochlor | 乙草胺 | GC-MSMS |
198 | Acrinathrin | 氟酯菊酯 | GC-MSMS |
199 | Alachlor | 甲草胺 | GC-MSMS |
200 | Aldrin | 艾氏ji剂 | GC-MSMS |
201 | Allethrin | 丙烯菊酯 | GC-MSMS |
202 | Azinphos-methyl | 保棉磷 | GC-MSMS |
203 | Benfluralin | 苯氟拉林 | GC-MSMS |
204 | α-BHC | α-六六六 | GC-MSMS |
205 | β-BHC | β-六六六 | GC-MSMS |
206 | γ-BHC(Lindane) | γ-六六六 | GC-MSMS |
207 | δ-BHC | δ-六六六 | GC-MSMS |
208 | Bifenox | 甲羧除草醚 | GC-MSMS |
209 | Bifenthrin | 联苯菊酯 | GC-MSMS |
210 | Bitertanol | 联苯三唑醇 | GC-MSMS |
211 | Bromacil | 除草定 | GC-MSMS |
212 | Bromophos-ethyl | 乙基溴硫磷 | GC-MSMS |
213 | Bromophos-methyl | 甲基溴硫磷 | GC-MSMS |
214 | Bromopropylate | 溴螨酯 | GC-MSMS |
215 | Bromuconazole | 糠菌唑 | GC-MSMS |
216 | Bupirimate | 乙嘧酚磺酸酯 | GC-MSMS |
217 | Butachlor | 丁草胺 | GC-MSMS |
218 | Butralin | 仲丁灵 | GC-MSMS |
219 | Cadusafos | 硫线磷 | GC-MSMS |
220 | Carbophenothion | 三硫lin磷 | GC-MSMS |
221 | Chinomethionat | 灭螨猛 | GC-MSMS |
222 | cis-Chlordane | 顺-氯丹 | GC-MSMS |
223 | trans-Chlordane | 反-氯丹 | GC-MSMS |
224 | Chlorfenapyr | 虫螨腈 | GC-MSMS |
225 | Chloropropylate | 氯丙基 | GC-MSMS |
226 | Chlorothalonil | 百菌清 | GC-MSMS |
227 | Chlorpropham | 氯苯胺灵 | GC-MSMS |
228 | Chlorpyrifos | 毒死蜱 | GC-MSMS |
229 | Chlorpyrifos-methyl | 甲基毒死蜱 | GC-MSMS |
230 | Chlorthal-dimethyl | 氯酞酸二甲酯 | GC-MSMS |
231 | Chlozolinate | 克氯得 | GC-MSMS |
232 | CPMC(Etrofol) | 害朴威 | GC-MSMS |
233 | Cyanofenphos | 氰硫磷 | GC-MSMS |
234 | Cyanophos | 杀螟腈 | GC-MSMS |
235 | Cyfluthrin | 氟氯氰菊酯 | GC-MSMS |
236 | Cyhalofop-butyl | 氰氟草脂 | GC-MSMS |
237 | λ-Cyhalothrin | 高效氯氟氰菊酯 | GC-MSMS |
238 | Cypermethrin | 氯氰菊酯 | GC-MSMS |
239 | α-cypermethrin | α-氯氰菊酯 | GC-MSMS |
240 | Cyproconazole | 环丙唑醇 | GC-MSMS |
241 | o,p’-DDD | o,p’-DDD | GC-MSMS |
242 | o,p’-DDE | o,p’-DDE | GC-MSMS |
243 | o,p'-DDT | o,p'-DDT | GC-MSMS |
244 | p,p’-DDE | p,p’-DDE | GC-MSMS |
245 | p,p’-DDT | p,p’-DDT | GC-MSMS |
246 | p,p'-DDD | p,p'-DDD | GC-MSMS |
247 | Deltamethrin | 溴氰菊酯 | GC-MSMS |
248 | Diazinon | 二嗪磷 | GC-MSMS |
249 | Dichlorvos | 敌敌wei畏 | GC-MSMS |
250 | Dicloran | 氯硝胺 | GC-MSMS |
251 | Dicofol | 三氯杀man螨醇 | GC-MSMS |
252 | Dicofol(DCBP) | o,p'-三氯杀man螨醇 | GC-MSMS |
253 | Dieldrin | 狄氏ji剂 | GC-MSMS |
254 | Difenoconazole | 苯醚甲环唑 | GC-MSMS |
255 | 2,6-Diisopropylnaphthalene | 2,6-二异丙基萘 | GC-MSMS |
256 | Dimethipin | 噻节因 | GC-MSMS |
257 | Diniconazole | 烯唑醇 | GC-MSMS |
258 | Dinitramine | 敌乐胺 | GC-MSMS |
259 | Diphenamid | 二苯胺 | GC-MSMS |
260 | Diphenylamine | 二苯胺 | GC-MSMS |
261 | Disulfoton | 乙拌lin磷 | GC-MSMS |
262 | Ditalimfos | 灭菌磷 | GC-MSMS |
263 | Dithiopyr | 氟硫草定 | GC-MSMS |
264 | Edifenphos | 敌瘟磷 | GC-MSMS |
265 | “-Endosulfan | 硫丹 | GC-MSMS |
266 | β-Endosulfan | β-硫丹 | GC-MSMS |
267 | Endosulfan-sulfate | 硫丹硫酸酯 | GC-MSMS |
268 | Endrin | 异狄氏ji剂 | GC-MSMS |
269 | EPN | 苯硫磷 | GC-MSMS |
270 | Epoxiconazole | 氟环唑 | GC-MSMS |
271 | Esfenvalerate | S-氰戊ju菊酯 | GC-MSMS |
272 | Ethion | 乙硫lin磷 | GC-MSMS |
273 | Ethoprophos | 灭线lin磷 | GC-MSMS |
274 | Etofenprox | 醚菊酯 | GC-MSMS |
275 | Etridiazole | 氯唑灵 | GC-MSMS |
276 | Etrimfos | 乙嘧硫磷 | GC-MSMS |
277 | Fenarimol | 氯苯嘧啶醇 | GC-MSMS |
278 | Fenbuconazole | 腈苯唑 | GC-MSMS |
279 | Fenitrothion | 杀螟硫磷 | GC-MSMS |
280 | Fenoxaprop-ethyl | 精噁唑禾草灵 | GC-MSMS |
281 | Fenpropathrin | 甲氰菊ju酯 | GC-MSMS |
282 | Fenpropimorph | 丁苯吗啉 | GC-MSMS |
283 | Fensulfothion | 苯磺硫磷 | GC-MSMS |
284 | Fenvalerate | 氰戊菊ju酯 | GC-MSMS |
285 | Flucythrinate | 氟氰戊菊ju酯 | GC-MSMS |
286 | Fluensulfone | 氟砜灵 | GC-MSMS |
287 | Fluroxypyr-meptyl | 氟草烟 | GC-MSMS |
288 | Flutolanil | 氟酰胺 | GC-MSMS |
289 | Fluvalinate | 氟胺氰菊酯 | GC-MSMS |
290 | Fluxapyroxad | 氟唑菌酰胺 | GC-MSMS |
291 | Fonofos | 地虫磷 | GC-MSMS |
292 | Formothion | 安硫磷 | GC-MSMS |
293 | Fthalide | 四氯苯酞 | GC-MSMS |
294 | Halfenprox | 苄螨醚 | GC-MSMS |
295 | Heptachlor | 七氯 | GC-MSMS |
296 | Heptachlorepoxide | 环氧七氯 | GC-MSMS |
297 | Heptenophos | 庚烯磷 | GC-MSMS |
298 | Hexazinone | 环嗪酮 | GC-MSMS |
299 | Imibenconazole | 亚胺唑 | GC-MSMS |
300 | Iprobenfos | 异稻瘟wen净 | GC-MSMS |
301 | Iprodione | 异菌脲 | GC-MSMS |
302 | Isofenphos | 异丙胺磷 | GC-MSMS |
303 | Isoprothiolane | 稻瘟灵 | GC-MSMS |
304 | Isotianil | 异噻菌胺 | GC-MSMS |
305 | Isoxathion | 异恶硫磷 | GC-MSMS |
306 | Kresoxim-methyl | 醚菌酯 | GC-MSMS |
307 | Malathion | 马拉硫liu磷 | GC-MSMS |
308 | Mefenacet | 苯噻酰草胺 | GC-MSMS |
309 | Mephosfolan | 甲氧麻黄huang酮 | GC-MSMS |
310 | Mepronil | 灭锈胺 | GC-MSMS |
311 | Metazachlor | 吡唑草胺 | GC-MSMS |
312 | Methacrifos | 虫螨畏 | GC-MSMS |
313 | Methidathion | 杀扑磷 | GC-MSMS |
314 | Methylpentachlorophenyl | 五氯硫代苯甲醚 | GC-MSMS |
315 | Metolachlor | 异丙甲草胺 | GC-MSMS |
316 | Mirex | 灭蚁灵 | GC-MSMS |
317 | Molinate | 草达灭 | GC-MSMS |
318 | Myclobutanil | 腈菌唑 | GC-MSMS |
319 | Napropamide | 敌草胺 | GC-MSMS |
320 | Nuarimol | 氟苯嘧啶醇 | GC-MSMS |
321 | Oxadiazon | 噁草酮 | GC-MSMS |
322 | Oxadixyl | 噁霜灵 | GC-MSMS |
323 | Oxyfluorfen | 乙氧氟草醚 | GC-MSMS |
324 | Paclobutrazol | 多效唑 | GC-MSMS |
325 | Parathion | 对硫lin磷 | GC-MSMS |
326 | Parathion-methyl | 甲基对硫lin磷 | GC-MSMS |
327 | Penconazole | 戊菌唑 | GC-MSMS |
328 | Pendimethalin | 二甲戊灵 | GC-MSMS |
329 | Penflufen | 氟唑菌苯胺 | GC-MSMS |
330 | Pentachloroaniline | 五氯苯胺 | GC-MSMS |
331 | Permethrin | 氯菊酯 | GC-MSMS |
332 | Phenothiol | 酚硫杀 | GC-MSMS |
333 | Phenothrin | 苯醚菊酯 | GC-MSMS |
334 | Phenthoate | 稻丰san散 | GC-MSMS |
335 | 2-Phenylphenol | 2-苯基苯酚 | GC-MSMS |
336 | Phorate | 甲拌lin磷 | GC-MSMS |
337 | Phosalone | 伏杀硫磷 | GC-MSMS |
338 | Phosmet | 亚胺硫lin磷 | GC-MSMS |
339 | Pirimiphos-ethyl | 乙基虫螨磷 | GC-MSMS |
340 | Pirimiphos-methyl | 甲基嘧啶磷 | GC-MSMS |
341 | Procymidone | 腐霉利 | GC-MSMS |
342 | Prometryn | 扑草净 | GC-MSMS |
343 | Propaphos | 丙虫磷 | GC-MSMS |
344 | Propiconazole | 丙环唑 | GC-MSMS |
345 | Prothiofos | 丙硫磷 | GC-MSMS |
346 | Pyraclofos | 吡唑硫磷 | GC-MSMS |
347 | Pyraflufen-ethyl | 吡草醚 | GC-MSMS |
348 | Pyrazophos | 吡菌磷 | GC-MSMS |
349 | Pyridaphenthion | 哒嗪硫磷 | GC-MSMS |
350 | Pyrimethanil | 嘧霉胺 | GC-MSMS |
351 | Pyrimidifen | 嘧螨醚 | GC-MSMS |
352 | Pyriproxyfen | 吡丙醚 | GC-MSMS |
353 | Pyroquilon | 咯喹酮 | GC-MSMS |
354 | Quinalphos | 喹硫磷 | GC-MSMS |
355 | Quintozene(PCNB) | 五氯硝基苯 | GC-MSMS |
356 | Salithion | 水杨硫磷 | GC-MSMS |
357 | Sedaxane | 氟唑环菌胺 | GC-MSMS |
358 | Silafluofen | 氟硅菊酯 | GC-MSMS |
359 | Tebuconazole | 戊唑醇 | GC-MSMS |
360 | Terbufos | 特丁硫lin磷 | GC-MSMS |
361 | Tetraconazole | 四氟醚唑 | GC-MSMS |
362 | Tetradifon | 三氯杀螨砜 | GC-MSMS |
363 | Tetramethrin | 胺菊酯 | GC-MSMS |
364 | Thenylchlor | 甲氧噻草胺 | GC-MSMS |
365 | Thifluzamide | 噻呋酰胺 | GC-MSMS |
366 | Thiometon | 甲基乙拌lin磷 | GC-MSMS |
367 | Tolclofos-methyl | 甲基立枯磷 | GC-MSMS |
368 | Triadimefon | 三唑酮 | GC-MSMS |
369 | Triadimenol | 三唑醇 | GC-MSMS |
370 | Triazophos | 三唑磷 | GC-MSMS |
371 | Tridiphane | 灭草环 | GC-MSMS |
372 | Triflumizole | 氟菌唑 | GC-MSMS |
373 | Trifluralin | 氟乐灵 | GC-MSMS |
374 | Vinclozolin | 乙烯菌核利 | GC-MSMS |
