英国Ossila材料PCE-12 OPV材料PBDB-T CAS:145929-80-4_Ossila-湖南远湘生物科技有限公司手机版

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只用于动物实验研究等

英国Ossila材料PCE-12 OPV材料PBDB-T CAS:145929-80-4

PBDB-T (PCE12) is now available, featuring:

Higher/lower molecular weights (so control experiments can be conducted)
High purity (PBDB-T is purified by Soxhlet extraction with methanol, hexane and chlorobenzene under an argon atmosphere)
Batch-specific GPC data (so you have confidence in what you are ordering. Also, GPC data is always convenient for your thesis and publications)
Large-quantity orders (so you can plan your experiments with polymers from the same batch)

Batch details

Batch	M_w	M_n	PDI	Stock Info
M1001	117,406	58,737	2.0	Low in stock
M1002	70,532	33,138	2.1	In stock

General Information

Full name	Poly[(2,6-(4,8-bis(5-(2-ethylhexyl)thiophen-2-yl)-benzo[1,2-b:4,5-b’]dithiophene))-alt-(5,5-(1’,3’-di-2-thienyl-5’,7’-bis(2-ethylhexyl)benzo[1’,2’-c:4’,5’-c’]dithiophene-4,8-dione)]
Synonyms	PBDB-T
Chemical formula	(C₆₈H₇₈O₂S₈)_n
CAS number	145929-80-4
HOMO / LUMO	HOMO = -5.33 eV, LUMO = -3.53 eV [1]; E_g = 1.8 eV
Solubility	Chloroform, Chlorobenzene, Dichlorobenzene and Trichlorobenzene
Classification / Family	Organic semiconducting materials, Low band-gap polymers, Organic Photovoltaics, Polymer solar cells, Perovskite solar cells, Hole-transport layer materials

英国Ossila材料PCE-12 OPV材料PBDB-T CAS:145929-80-4

Applications

PBDB-T (PCE12) is one of the highest-performing donor polymers for OPVs, having reported efficiencies exceeding 12% [1, 2], and a certified efficiency approaching 11% [3]. These efficiencies were achieved when PBDB-T was used in conjunction with recently-reported non-fullerene acceptors (including ITIC) in inverted architecture devices. These devices also exhibited excellent thermal stability, making the combination a promising candidate for the proposed 10/10 target of 10% efficiency and 10-year lifetimes.

PBTB-T (PCE12) is easy to process, simplifying device fabrication while simultaneously providing high performance.

Due to good HOMO alignment with the valence band of commonly-used perovskites, this polymer could also be used as a hole-transporting material in perovskite solar cells .

Usage Details

The device structure of the certified devices was:

ITO / ZnO (30 nm) / PBDB-T:ITIC (100 nm) / MoO₃ (10 nm) / Al (100 nm)

PBDB-T:ITIC solution details:

Blend ratio: 1:1,
Concentration: 20 mg/ml,
Solvent: Chlorobenzene
Additive: 0.5% Diiodooctane.

Literature and Reviews

Energy-Level Modulation of Small-Molecule Electron Acceptors to Achieve over 12% Efficiency in Polymer Solar Cells, S. Li et al, Adv. Mater., 28, 9423–9429 (2016); DOI: 10.1002/adma.201602776.
Ternary Polymer Solar Cells based on Two Acceptors and One Donor for Achieving 12.2% Efficiency, W. Zhao et al., Adv. Mater., 29, 1604059 (2017); DOI: 10.1002/adma.201604059.
Fullerene-Free Polymer Solar Cells with over 11% Efﬁciency and Excellent Thermal Stability, W. Zhao et al., Adv. Mater., 28, 4734–4739 (2016); DOI: 10.1002/adma.201600281.

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